Preheat an indoor or outdoor grill to high. Prepare the rice pilaf according to package directions, adding the curry powder and turmeric instead of the seasoning packet.
Once you have the rice pilaf working, start the chicken: In a large baggie, combine the grill seasoning, chili powder, paprika and brown sugar.
Place the chicken breasts in the baggie and give them a good shimmy shake. Spray or oil down your grill then place the chicken on it and cook for 6-7 minutes on each side, until cooked through.
Fluff the rice with a fork and stir in the smoked almonds and orange segments. Serve the chicken with a spoonful of rice and a piece of Orange-Scented Cornbread alongside.