Rachael's last mystery taster of the season is a big one -- Dustin Hoffman! The clue that finally gave it away was Dustin's classic line, "I'm very proud to be a woman," from one of Rach's favorite films, Tootsie. She asks Dustin if he ever likes to watch his own films from time to time, and when he says "I do like to watch myself ..." his answer has Rachael blushing!

When Rachael asks Dustin what's in his personal movie library, Dustin mentions a few of his favorites and admits to an "illegal" activity ...

"Don't tell anyone!"

Dustin's wife Lisa joins them at the kitchen table, and explains how she came up with the idea for her innovative skin care product. "When we decided to get married, we decided we wanted as traditional a marriage -- and family -- as possible, which meant traveling and staying together. I got packing down to a science, except for toiletries and beauty products I could never get that right." Lisa tells Rachael that she had a dream one night that she had everything she needed for 24 hours in one package -- the exact dosage for daytime and nighttime products. Now Lisa's dream is a reality with her own line of 24-Hour Night & Day Skin Care Packettes!

Rachael asks Lisa, "Do you put the goop on Dustin?"

"She did that even before she invented this!" Dustin admits. "I like it. I'm a metrosexual so I'm comfortable with it. I had a pedicure just yesterday!"

Web exclusive! Twenty-five years ago, Rachael Ray technical director Richie Wirth worked with Dustin on Tootsie. The two get reacquainted during a break in the taping. "I knew it had to be you!"